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Registros recuperados: 39 | |
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Donval, Jean-pierre; Guyader, Vivien. |
“Headspace” technique is one of the methods for the onboard measurement of hydrogen (H2) and methane (CH4) in deep seawater. Based on the principle of an automatic headspace commercial sampler, a specific device has been developed to automatically inject gas samples from 300 ml syringes (gas phase in equilibrium with seawater). As valves, micro pump, oven and detector are independent, a gas chromatograph is not necessary allowing a reduction of the weight and dimensions of the analytical system. The different steps from seawater sampling to gas injection are described. Accuracy of the method is checked by a comparison with the “purge and trap” technique. The detection limit is estimated to 0.3 nM for hydrogen and 0.1 nM for methane which is close to the... |
Tipo: Text |
Palavras-chave: Gas; Seawater; Headspace method. |
Ano: 2017 |
URL: http://archimer.ifremer.fr/doc/00354/46523/46287.pdf |
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Donval, Jean-pierre; Charlou, Jean-luc; Lucas, L.. |
Headspace technique is a common method to analyze light hydrocarbons in deep marine sediments. The use of an automatic headspace sampler instead of a manual injection is the guarantee for a better repeatability and furthermore it is less time consuming. But to increase the sensitivity and therefore, to achieve a better detection limit, it is necessary to optimize the automatic headspace sampler parameters. The theory of design of experiments was applied here by studying them. As a response, methane, which is an important gas in marine sediments, was chosen for its short analysis time. Regarding the parameters for automatic headspace sampler, eight variables were selected and then, a screening of them was carried out with a fractional factorial design to... |
Tipo: Text |
Palavras-chave: Design of experiments; Headspace technique; Gas; Sediments. |
Ano: 2008 |
URL: http://archimer.ifremer.fr/doc/2008/publication-6235.pdf |
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Alain, Karine; Pignet, Patricia; Zbinden, M; Quillevere, M; Duchiron, F; Donval, Jean-pierre; Lesongeur, Francoise; Raguenes, Gerard; Crassous, Philippe; Querellou, Joel; Cambon-bonavita, Marie-anne. |
A novel thermophilic, anaerobic, strictly chemoorganoheterotrophic bacterium, designated as AM1114(T), was isolated from a deep-sea hydrothermal vent sample from the East-Pacific Rise (EPR 13degrees N). The cells were long (3-10 mum) rods, motile with peritrichous flagella, and exhibited a Gram-negative cell wall ultrastructure. In the late stationary phase of growth, cells formed an ovoid, refractile, terminal endospore. They grew at 45-65 degreesC inclusive (optimum 55-60 degreesC; doubling time approx. 45 min), at pH 4.5-8.0 inclusive (optimum pH 7.5-8.0) and at sea salt concentrations of 20-60 g l(-1) inclusive (optimum 25-30 g l(-1)). Strain AM1114(T) was an obligately heterotrophic bacterium able to ferment a mixture of 20 amino acids, complex... |
Tipo: Text |
Palavras-chave: Caminicella sporogenes; Clostridiales; Thermophile; Deep sea hydrothermal vent. |
Ano: 2002 |
URL: http://archimer.ifremer.fr/doc/2002/publication-528.pdf |
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Bougault, Henri; Appriou, P; Bienvenu, P; Cambon, Pierre; Charlou, Jean-luc; Collette, B; Donval, Jean-pierre; Dosso, Laure; Floch, G; Fouquet, Yves. |
Tipo: Text |
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Ano: 1990 |
URL: http://archimer.ifremer.fr/doc/00070/18105/15653.pdf |
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Konn, Cecile; Charlou, Jean-luc; Donval, Jean-pierre; Holm, Nils G.. |
The analysis of the dissolved organic fraction of hydrothermal fluids has been considered a real challenge due to sampling difficulties, complexity of the matrix, numerous interferences and the assumed ppb concentration levels. The present study shows, in a qualitative approach, that Stir Bar Sorptive Extraction (SBSE) followed by Thermal Desorption - Gas Chromatography - Mass Spectrometry (TD-GC-MS) is suitable for extraction of small sample volumes and detection of a wide range of volatile and semivolatile organic compounds dissolved in hydrothermal fluids. In a case study, the technique was successfully applied to fluids from the Rainbow ultramafic-hosted hydrothermal field located at 36 degrees 14'N on the Mid-Atlantic Ridge (MAR). We show that... |
Tipo: Text |
Palavras-chave: Sample preparation; Extraction; Organic compounds; Hydrothermal fluids; Ultramafic rocks. |
Ano: 2012 |
URL: http://archimer.ifremer.fr/doc/00114/22514/20196.pdf |
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Roussel, Erwan; Konn, Cecile; Charlou, Jean-luc; Donval, Jean-pierre; Fouquet, Yves; Querellou, Joel; Prieur, Daniel; Cambon-bonavita, Marie-anne. |
The distribution of Archaea and methanogenic, methanotrophic and sulfate-reducing communities in three Atlantic ultramafic-hosted hydrothermal systems (Rainbow, Ashadze, Lost City) was compared using 16S rRNA gene and functional gene (mcrA, pmoA and dsrA) clone libraries. The overall archaeal community was diverse and heterogeneously distributed between the hydrothermal sites and the types of samples analyzed (seawater, hydrothermal fluid, chimney and sediment). The Lost City hydrothermal field, characterized by high alkaline warm fluids (pH>11; T<95 °C), harbored a singular archaeal diversity mostly composed of unaffiliated Methanosarcinales. The archaeal communities associated with the recently discovered Ashadze 1 site, one of the deepest active... |
Tipo: Text |
Palavras-chave: Archaea; Hydrothermal vent; Mid-Atlantic Ridge; 16S rRNA gene; Sediment; Ultramafic. |
Ano: 2011 |
URL: http://archimer.ifremer.fr/doc/00067/17836/15573.pdf |
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Boulart, Cedric; Briais, Anne; Chavagnac, Valerie; Revillon, Sidonie; Ceuleneer, Georges; Donval, Jean-pierre; Guyader, Vivien; Barrere, Fabienne; Ferreira, Nicolas; Hanan, Barry; Hemond, Christophe; Macleod, Sarah; Maia, Marcia; Maillard, Agnes; Merkuryev, Sergey; Park, Sung-hyun; Ruellan, Etienne; Schohn, Alexandre; Watson, Sally; Yang, Yun-seok. |
Using a combined approach of seafloor mapping, MAPR and CTD survey, we report evidence for active hydrothermal venting along the 130°-140°E section of the poorly-known South-East Indian Ridge (SEIR) from the Australia-Antarctic Discordance (AAD) to the George V Fracture Zone (FZ). Along the latter, we report Eh and CH4 anomalies in the water column above a serpentinite massif, which unambiguously testify for ultramafic-related fluid flow. This is the first time that such circulation is observed on an intermediate-spreading ridge. The ridge axis itself is characterized by numerous off-axis volcanoes, suggesting a high magma supply. The water column survey indicates the presence of at least ten distinct hydrothermal plumes along the axis. The CH4:Mn ratios... |
Tipo: Text |
Palavras-chave: Hydrothermal plumes; Mid-ocean ridges; South-East Indian Ridge. |
Ano: 2017 |
URL: http://archimer.ifremer.fr/doc/00387/49821/50400.pdf |
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Ruffine, Livio; Donval, Jean-pierre; Croguennec, Claire; Burnard, Pete; Lu, Hailong; Germain, Yoan; Legoix, Ludovic N.; Bignon, Laurent; Çağatay, M. Namık; Marty, Bernard; Madre, David; Pitel-roudaut, Mathilde; Henry, Pierre; Géli, Louis. |
The authors regret a mistake on the value of δ13C of methane for one of the investigated gas samples. This concerns sample MRS-DV3-PE03, taken as end member and for which the correct methane δ13C value is -41.9‰ and not -34‰. The sample was collected at in situ pressure (~100 bars) from a CO2-rich seep, in a liquid state. The mistake likely results from a partial extraction (i.e. done by expansion of the sampler volume to allow vaporization) of the pressurized sample for subsampling. Additional analyses have been carried out from fully vaporized samples. This error has resulted in updating the geochemical diagrams used for the discussion, and revising both the gas origin for sample MRS-DV3-PE03 and the section entitled “Delineation of sources, reservoirs... |
Tipo: Text |
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Ano: 2018 |
URL: https://archimer.ifremer.fr/doc/00471/58253/61076.pdf |
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Jean Baptiste, P; Fourre, E; Dapoigny, A; Charlou, Jean-luc; Donval, Jean-pierre. |
As part of a multidisciplinary project aimed at studying mid-ocean ridge processes near the Azores, fifty water column profiles were analyzed for He-3/He-4 ratios in dissolved helium (a well-known hydrothermal tracer) from 36 degrees N to 40 degrees N along the Mid-Atlantic Ridge (MAR) and over the Azores Plateau. As expected, large delta(3) He anomalies could be observed over the Rainbow, Lucky Strike, and Menez Gwen hydrothermal sites. The main finding of the present study is the discovery of a large hydrothermal 3 He plume north of the Acor Fracture Zone (north AFZ site), with a CH4/He-3 ratio indicative of a basaltic-hosted hydrothermal system. Clear He-3 and CH4 anomalies, likely corresponding to unknown venting sites too, were also detected in the... |
Tipo: Text |
Palavras-chave: Hydrothermal processes; Helium 3; Mid ocean ridges. |
Ano: 2008 |
URL: http://archimer.ifremer.fr/doc/2008/publication-3876.pdf |
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Radford Knoery, Joel; German, C; Charlou, Jean-luc; Donval, Jean-pierre; Fouquet, Yves. |
Through the deep ocean, hydrothermal plumes disperse high concentrations of key chemical tracers including He-3, CH4, Mn, Fe, H2S, etc. This paper focuses on the distribution and behavior of total dissolved sulfide (sulfide hereafter) in hydrothermal plumes to show that its plume concentration decreases to subnanomolar a few kilometers from the vents. We also report on sulfide removal rates determined at in situ conditions; we observe that they are two orders of magnitude greater than for open ocean seawater, consistent with sulfide being detected only in the vicinity of hydrothermal vents. From our observations, we infer that the sole presence of sulfide in hydrothermal plumes locates active venting at the kilometer scale. |
Tipo: Text |
Palavras-chave: Chemical oceanography; Mid ocean ridges; Metals; Helium isotopes; Methane; Tracers; Hydrogen sulphide; Plumes; Hydrothermal activity. |
Ano: 2001 |
URL: https://archimer.ifremer.fr/doc/2001/publication-688.pdf |
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Bayon, Germain; Birot, Dominique; Ruffine, Livio; Caprais, Jean-claude; Ponzevera, Emmanuel; Bollinger, C.; Donval, Jean-pierre; Charlou, Jean-luc; Voisset, Michel; Grimaud, S.. |
For many trace elements, continental margins are the location of intense exchange processes between sediment and seawater, which control their distribution in the water column, but have yet to be fully understood. In this study, we have investigated the impact of fluid seepage at cold seeps on the marine cycle of neodymium. We determined dissolved and total dissolvable (TD) concentrations for REE and well-established tracers of fluid seepage (CH4, TDFe, TDMn), and Nd isotopic compositions in seawater samples collected above cold seeps and a reference site (i.e. away from any fluid venting area) from the Niger Delta margin. We also analyzed cold seep authigenic phases and various core-top sediment fractions (pore water, detrital component, easily leachable... |
Tipo: Text |
Palavras-chave: Rare earth elements; Neodymium isotopes; Seawater; Cold seeps; Fe-Mn oxyhydroxides; Benthic fluxes. |
Ano: 2011 |
URL: http://archimer.ifremer.fr/doc/00066/17754/15571.pdf |
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Konn, Cecile; Fourre, E.; Jean-baptiste, P.; Donval, Jean-pierre; Guyader, Vivien; Birot, Dominique; Alix, Anne-sophie; Gaillot, Arnaud; Perez, Florian; Dapoigny, A.; Pelleter, Ewan; Resing, J. A.; Charlou, Jean-luc; Fouquet, Yves. |
The study area is close to the Wallis and Futuna Islands in the French EEZ. It exists on the western boundary of the fastest tectonic area in the world at the junction of the Lau and North-Fiji basins. At this place, the unstable back-arc accommodates the plate motion in three ways: (i) the north Fiji transform fault, (ii) numerous unstable spreading ridges, and (iii) large areas of recent volcanic activity. This instability creates bountiful opportunity for hydrothermal discharge to occur. Based on geochemical (CH4, TDM, 3He) and geophysical (nephelometry) tracer surveys: (1) no hydrothermal activity could be found on the Futuna Spreading Center (FSC) which sets the western limit of hydrothermal activity; (2) four distinct hydrothermal active areas were... |
Tipo: Text |
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Ano: 2016 |
URL: http://archimer.ifremer.fr/doc/00347/45848/45505.pdf |
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Auzende, Jean-marie; Ishibashi, J; Beaudouin, Y; Charlou, Jean-luc; Delteil, J; Donval, Jean-pierre; Fouquet, Yves; Gouillou, Jp; Ildefonse, B; Kimura, H; Nishio, Y; Knoery, Joel; Ruollan, E. |
In 1995, a joint French‐Japanese cruise (ManusFlux) explored the Manus Spreading Center and some sites of the South Eastern Rift in the Manus Basin off the coast of Papua New Guinea (Figure 1) with the Japanese submersible [Auzende et al., 1996; Gamo et al., 1997]. In the framework of this joint project, called New STARMER, the French and Japanese teams completed the Manaute cruise with the R/V LAtalante and the Ifremer submersible Nautile in April and May 2000. The Manaute cruise explored and sampled volcanic and hydrothermal sites in the eastern part of Manus Basin and on the spreading axis of the Western Ridge (WR). The eastern part of the Manus Basin (Figure 2) was interpreted as a stretched‐back arc basin crust showing alternatively elongated ridges... |
Tipo: Text |
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Ano: 2000 |
URL: http://archimer.ifremer.fr/doc/00069/18055/15597.pdf |
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Fouquet, Yves; Barriga, F; Charlou, Jean-luc; Elderfield, H; German, C.r; Ondreas, Helene; Parson, L; Radford-knoery, Joel; Relvas, J; Ribeiro, A; Schultz, A; Apprioual, R; Cambon, P; Costa, I; Donval, Jean-pierre; Douville, E; Landure, Jy; Normand, A; Pelle, H; Ponsevera, E. |
Tipo: Text |
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Ano: 1998 |
URL: http://archimer.ifremer.fr/doc/00070/18133/15681.pdf |
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De Prunele, Alexis; Ruffine, Livio; Riboulot, Vincent; Peters, Carl A.; Croguennec, Claire; Guyader, Vivien; Pape, Thomas; Bollinger, Claire; Bayon, Germain; Caprais, Jean-claude; Germain, Yoan; Donval, Jean-pierre; Marsset, Tania; Bohrmann, Gerhard; Geli, Louis; Rabiu, Abdulkarim; Lescanne, Marc; Cauquil, Eric; Sultan, Nabil. |
The Niger Delta is one of the largest hydrocarbon basin offshore Africa and it is well known for the presence of active pockmarks on the seabed. During the Guineco-MeBo cruise in 2011, long cores were taken from a pockmark cluster in order to investigate the state of its current activity. Gas hydrates, oil and pore-water were sampled for geochemical studies. The resulting dataset combined with seismic data reveal that shallow hydrocarbon migration in the upper sedimentary section was focused exclusively within the pockmarks. There is a clear tendency for gas migration within the hydrate-bearing pockmarks, and oil migration within the carbonate-rich one. This trend is interpreted as a consequence of hydrate dissolution followed by carbonate precipitation... |
Tipo: Text |
Palavras-chave: Anaerobic oxidation of methane; Cluster of pockmarks; Fluid flow; Gas hydrates; Pore-water profiles; Transient state. |
Ano: 2017 |
URL: http://archimer.ifremer.fr/doc/00365/47647/47676.pdf |
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Bourry, Christophe; Chazallon, Bertrand; Charlou, Jean-luc; Donval, Jean-pierre; Ruffine, Livio; Henry, Pierre; Geli, Louis; Cagatay, M. Namik; Inan, Sedat; Moreau, Myriam. |
Gas hydrates and gas bubbles were collected during the MARNAUT cruise (May-June 2007) in the Sea of Marmara along the North Anatolian Fault system, Turkey. Gas hydrates were sampled in the western part of the Sea of Marmara (on the Western High), and three gas-bubble samples were recovered on the Western High, the Central High (center part of the Sea of Marmara) and in the Cinarcik Basin (eastern part of the Sea of Marmara). Methane is the major component of hydrates (66.1%), but heavier gases such as C-2, C-3, and i-C-4 are also present in relatively high concentration. The methane contained within gas hydrate is clearly thermogenic as evidenced by a low C-1/C-2 + C-3 ratio of 3.3, and carbon and hydrogen isotopic data (delta C-13(CH4) of -44.1 parts per... |
Tipo: Text |
Palavras-chave: Isotopes; Thermogenic gas; Gas bubbles; Gas hydrate; Sea of Marmara. |
Ano: 2009 |
URL: http://archimer.ifremer.fr/doc/2009/publication-6844.pdf |
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Jean-baptiste, Philippe; Fourre, Elise; Charlou, Jean-luc; Donval, Jean-pierre; Correge, Thierry. |
Historical descriptions of the Clipperton lagoon appear to converge on the fact that it became isolated from the surrounding ocean around 1858. Since then, because of the high precipitation rate which largely exceeds evaporation in this region of the eastern tropical Pacific, a brackish lens has formed on top of the saline oceanic waters. In 1980, literature data show that the thickness of this water body was reaching 14 m. During the 2005 Etienne's Clipperton expedition, we collected lagoon water on two vertical profiles. Salinity, delta O-18 and tritium analyses were performed on these samples with the objective of gaining further insight into the lagoon hydrology and age of the deep waters. The upper 15 m were characterized by low salinities (5.4 +/-... |
Tipo: Text |
Palavras-chave: Oxygen isotopes; Tritium; Enclosed lagoon hydrology; Clipperton atoll. |
Ano: 2009 |
URL: http://archimer.ifremer.fr/doc/2009/publication-6457.pdf |
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Registros recuperados: 39 | |
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